On 3 September 2006 in Lausanne Don became World Champion after finishing 17 seconds in front of Hamish Carter. Following the swim, he was in the lead group on the bike but missed the initial break. He bridged the gap alone and caught the lead group on lap 5 out of 6, then took the lead along with Carter on the run, breaking clear about halfway through.
However his performance was overshadowed by a three-month ban a few weeks later for missing three out of competition drug tests within an 18-month period prior to the race. The ban expired on 25 December 2006, but a byelaw meant that Don remained ineligible for Olympic selection. On Friday, 25 May 2007, Don was cleared by the British Olympic Association for selection for future Olympic Games after appealing against a ban for missing doping tests. The BOA appeals panel whilst clearing Don to compete in future Olympic Games criticised him for being "indisputably careless and irresponsible".