Mićalović is a close friend of actresses Zorana Bečić and Ana Franić. In 2008 she married fellow actor Vojin Ćetković in Belgrade and took his surname, thus she is commonly dubbed Sloboda Mićalović–Ćetković. In the February 2010 she gave birth to twin girls, Mila and Vera. The couple and their children live in Novi Beograd, Belgrade.
In 2008 and 2009 Mićalović starred in the RTS television series Ranjeni orao, which became the most-watched Serbian television series of all time. She was also considered for the role of Katarina in 2009 film Sveti Georgije ubiva aždahu, eventually given to Nataša Janjić. In 2011/2012 she starred in television series Nepobedivo srce.
