In the 2014 indoor season, she improved her personal best at 4.55 m. In the 2014 outdoor season, she improved her personal best at 4.57 m and established a new personal best at 4.60 m at the Diamond League meeting at New York City, where she placed 4th. She competed for the first time at the European Athletics Team Championships 1st league, held in Tallinn, representing Greece and winning with a 4.55 m jump. She managed to improve her PB again at the Diamond league in Glasgow with a jump at 4.65 m, taking the third place. One week before the European Championships she set another PB at 4.71 m, equaling the outdoor Greek national record.
At the 2014 European Championships, she had an easy qualification, while in the final she had her first success in major events as a woman by winning the silver medal with 4.60 m, losing the gold medal in the very last jump of the event, made by Anzhelika Sidorova. She later won the Birmingham Diamond League meeting with 4.57 m and took the third place at the Diamond league final, held in Zurich with 4.67 m. With these results, she took the second place overall at the Diamond League series, only behind Fabiana Murer. During 2014, she jumped 10 times above 4.55 m, while her former PB was at 4.51 m.